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Temperature dependent electron cyclotron resonance etching of InP, GaP, and GaAs

Identifieur interne : 019D02 ( Main/Repository ); précédent : 019D01; suivant : 019D03

Temperature dependent electron cyclotron resonance etching of InP, GaP, and GaAs

Auteurs : RBID : Pascal:97-0099670

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English descriptors

Abstract

Electron cyclotron resonance etching of InP, GaP, and GaAs in Ar, Ar/Cl 2, Ar/Cl2/H2, and Ar/Cl2/H2/CH4 plasmas is reported for substrate temperatures from 10 to 170 °C. Etch rates increased as a function of temperature for GaP and GaAs in an Ar/Cl2 plasma. With the addition of H2 or H2/CH4 to the plasma, the GaP and GaAs etch rates decreased and were essentially temperature independent. In comparison, InP etch rates showed a strong temperature dependence regardless of plasma chemistry. At 170 °C, InP etch rates were greater than GaP and GaAs in the Ar/Cl2/H2 and Ar/Cl2/H 2/CH4 plasmas. Atomic force microscopy was used to determine the root-mean-square roughness of the etched surfaces. The etched surface morphology for InP was strongly dependent on temperature and plasma chemistry while smooth pattern transfer was obtained for a wide range of plasma conditions for GaAs and GaP. © 1996 American Vacuum Society

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Pascal:97-0099670

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<title xml:lang="en" level="a">Temperature dependent electron cyclotron resonance etching of InP, GaP, and GaAs</title>
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<name sortKey="Shul, R J" uniqKey="Shul R">R. J. Shul</name>
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<name sortKey="Howard, A J" uniqKey="Howard A">A. J. Howard</name>
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<name sortKey="Barnes, P A" uniqKey="Barnes P">P. A. Barnes</name>
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<name sortKey="Seng, W" uniqKey="Seng W">W. Seng</name>
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<title level="j" type="abbreviated">J. vac. sci. technol., A, Vac. surf. films</title>
<title level="j" type="main">Journal of vacuum science and technology. A. Vacuum, surfaces, and films</title>
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<term>Argon</term>
<term>Chemical reactions</term>
<term>Chlorine</term>
<term>Electron cyclotron-resonance</term>
<term>Etching</term>
<term>Experimental study</term>
<term>Gallium arsenides</term>
<term>Gallium phosphides</term>
<term>Hydrogen</term>
<term>Indium phosphides</term>
<term>Methane</term>
<term>Morphology</term>
<term>Plasma</term>
<term>Temperature dependence</term>
<term>Temperature range 0273-0400 K</term>
<term>Temperature range 0400-1000 K</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Indium phosphure</term>
<term>Gallium phosphure</term>
<term>Gallium arséniure</term>
<term>Gravure</term>
<term>Argon</term>
<term>Chlore</term>
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<term>Domaine température 0273-0400 K</term>
<term>Domaine température 0400-1000 K</term>
<term>8165C</term>
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<div type="abstract" xml:lang="en">Electron cyclotron resonance etching of InP, GaP, and GaAs in Ar, Ar/Cl
<sub> 2</sub>
, Ar/Cl
<sub>2</sub>
/H
<sub>2</sub>
, and Ar/Cl
<sub>2</sub>
/H
<sub>2</sub>
/CH
<sub>4</sub>
plasmas is reported for substrate temperatures from 10 to 170 °C. Etch rates increased as a function of temperature for GaP and GaAs in an Ar/Cl
<sub>2</sub>
plasma. With the addition of H
<sub>2</sub>
or H
<sub>2</sub>
/CH
<sub>4</sub>
to the plasma, the GaP and GaAs etch rates decreased and were essentially temperature independent. In comparison, InP etch rates showed a strong temperature dependence regardless of plasma chemistry. At 170 °C, InP etch rates were greater than GaP and GaAs in the Ar/Cl
<sub>2</sub>
/H
<sub>2</sub>
and Ar/Cl
<sub>2</sub>
/H
<sub> 2</sub>
/CH
<sub>4</sub>
plasmas. Atomic force microscopy was used to determine the root-mean-square roughness of the etched surfaces. The etched surface morphology for InP was strongly dependent on temperature and plasma chemistry while smooth pattern transfer was obtained for a wide range of plasma conditions for GaAs and GaP. © 1996 American Vacuum Society</div>
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<s0>Electron cyclotron resonance etching of InP, GaP, and GaAs in Ar, Ar/Cl
<sub> 2</sub>
, Ar/Cl
<sub>2</sub>
/H
<sub>2</sub>
, and Ar/Cl
<sub>2</sub>
/H
<sub>2</sub>
/CH
<sub>4</sub>
plasmas is reported for substrate temperatures from 10 to 170 °C. Etch rates increased as a function of temperature for GaP and GaAs in an Ar/Cl
<sub>2</sub>
plasma. With the addition of H
<sub>2</sub>
or H
<sub>2</sub>
/CH
<sub>4</sub>
to the plasma, the GaP and GaAs etch rates decreased and were essentially temperature independent. In comparison, InP etch rates showed a strong temperature dependence regardless of plasma chemistry. At 170 °C, InP etch rates were greater than GaP and GaAs in the Ar/Cl
<sub>2</sub>
/H
<sub>2</sub>
and Ar/Cl
<sub>2</sub>
/H
<sub> 2</sub>
/CH
<sub>4</sub>
plasmas. Atomic force microscopy was used to determine the root-mean-square roughness of the etched surfaces. The etched surface morphology for InP was strongly dependent on temperature and plasma chemistry while smooth pattern transfer was obtained for a wide range of plasma conditions for GaAs and GaP. © 1996 American Vacuum Society</s0>
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